Friday, November 15, 2019

Research on Altered Granites

Research on Altered Granites Visible yellow radial U- minerals (up to 1 % U )was recorded coating the fractures in the sheared granites, border on the two sides by milky quartz veins, which play as septa for U- minerals migration. From the mineralogical point of view, the sheared granite rich in; a) uranium (meta-autunite, kasolite and phurcalite) , b) thorium (uranothorite) and c) base metals (wolframite, columbite, fergusonite and Plumbopyrochlore minerals) in addition to zircon, allanite, rutile, fluorite, fluro-apatite, phlogopite and iron oxide minerals (hematite, ilmenite, goethite and magnetite )(Table.1).Meta-autunite occurs as lemon-yellow to greenish yellow, subhedral crystals formed as dehydration pseudomorphs after autunite (Fig,6a) and usually associated with kasolite. Phurcalite occurs as light brown subhedral to anhedral crystals of calcium uranium phosphate (Fig,6b) and usually associated with iron oxides. The altered granites are enriched in most major oxides (Fe2O3, Tio2, ,Mn, Mg, CaO and P2O5,) except SiO2 and Na2O than fresh granites (Fig.7) manifesting ferrugination, calcification ,desilicification and illitization .Also the fresh granites are depleted in most trace elements (Ni, Cr, Sr, Zr, Y, Ga, Zn, Pb, and Cu) except Nb than altered ones. Based on major element data, the main characteristic features of the studied altered granites are higher in Fe/Mg ratio (15 av.), lower in SiO2(av.52.8 %)andNa2O /K2O ( av.0.16) than fresh granites Table 2 ) . Fig. 6: Photomicrographs showing; a) meta-autunite crystal surrounded by phurcalite mineral in altered granites. C.N., X=40 and b) phurcalite mineral associated with iron oxide in altered granites. C.N., X=40. Table (1): Shows the result of minerals occurrences in the study area. Minerals group Rock types Minerals Uranium minerals Altered granite Meta-autunite, Phurcalite and Kasolite Thorium minerals Uranothorite Base Metals Altered granite Wolframite Black Jasper Cassiterite, Wolframite, Zincite, Ni-chromite and Cr-spinel Red Jasper Ni-Chromite and Cr-spinel Milky quartz Galena, Pyrite, pyrrhotite and Sphalerite Copper Minerals Milky quartz covellite, bornite Red Jasper crysocolla Black Jasper Atacamite, Paratacamite, and cuprite Native minerals Black Jasper and Milky quartz Gold and Nickel Nb-Ta minerals Altered granites Plumbopyrochlore, Columbite and Fergusonite REEs-Bearing Minerals Alkali feldspar granites Zircon, Fluorite syenogranites Zircon, allanite Altered granites Zircon, Allanite, Rutile and Fluorite Stream sediments Zircon, Monazite Black Jasper Xenotime Red Jasper Iron Minerals Altered granites Hematite, Ilmenite, Goethite and Magnetite Black Jasper Hematite, Magnetite Red Jasper Hematite, Magnetite and Goethite Milky quartz Hematite Fig.( 7 ) The enrichment and depletion of major oxides and trace elements of altered granites to the fresh granites samples. Fig.( 8 ) Bar- diagram showing the trace elements distribution of red and black jasper. The content of HFSE in both fresh and altered granites (Nb (36-10 ppm), Zr (316- 759 ppm), Y(69- 220 ppm) ,U (8-ppm) respectively as well as low Rb/Sr ratio (1.04-0.45) and K/ Rb ratio (0.03-0.04) (Table 2) suggest that the fresh granites are primarily derived from felsic source .On the other side, these criteria in the altered granites are critical for uranium exploration . The black jasper more richer than red one in Ni (av.1004 -81ppm),Cr(av.8575 -853ppm),Zn (av.144 -80 ppm), Cu(av.1106- 35 ppm), Co(av.371-0.0 ppm), Au(1.04 -0.5 ppm) and U(40- 8800ppm)respectively (Table 2,Fig.8 ). The latest event invades the WNW-ESE shear zone was the intrusion of silica and jasper veins with different magnitude. The excess of released quartz can migrate as colloidal silica to precipitate later in the tension fractures as jasperoid vein at upper structural levels under low temperature condition .Silicification along the main shear zone has a noticeable amount of liberated secondary silica occurs as fine crystals associated with the large primary quartz crystals and characterized by the existence of three generations of silica veins differ in color, mineralization and age. 1)The milky quartz veins are the first phase (the youngest one), mainly barren, running WNW and dipping 70 °/ SSW direction, highly brecciated (2-5 Km in length, 0.25-3 m in width)and common only at the southern border of the shear zone. 2) The red jasper veins(second phase) have E-W ,WNW,NW and NE trends (Fig.5), dipping 50-75/N or S , 45 °/ SSW, SW and SE direction respectively. They fractured, fragmented, discontinuous, brecciated,(7km in length, 0.30-3 m in width) and rich in Cr, , Ni, Sn, Zn and Cu- mineralization (Fig.6) (some parts of red jasper are rich by vugs (physical tap) that are filled by mineralization. These veins exhibit combinations of more than one style; orbicular and brecciated. Brecciated red jasper (Plate 4.a) can vary from soft swirls of color to dramatically fragmented shades of rich brown, brick red and cream colors. Deeply integrated colors come from organic materials and iron oxides imbedded in the stones. Ore microscopic investigation reveals that; quartz crystals occur as anhedral cryptocrystalline associated and stained by iron oxide. Sometimes cryptocrystalline crystals of amorphous silica form banding. Iron oxide occurs as black crystalline minerals and staining of quartz. 3) The black jasper(oldest one) is represented by 1.8 km in length, 0.5-10 m in width, trending N45 °W ,dipping 50 °-65 ° /SW (Figs.5), and rich in Cr, Ni, Cu and Au mineralization, Fig.7).They are concentrated only in the eastern part of G. Um Bakra shear zone and less abundant in length than milky and red veins. The black jasper are vuggy than milky and red silica veins and these vugs filled by calcite minerals. The apical parts of the veins are intensely weathered, oxidized, brecciated fragments (Plate.4b) and decomposed to forming gossans. Petrographically, quartz occurs as cryptocrystalline and polycrystalline forming spherulitic texture and associated with iron oxide. Iron oxide associated with quartz and sometimes forming network or needle (Plate .4c). Cr- spinel with blood red color was observed and having darker boundaries with quartz (Plate.4d).Ore microscopic study reveals the presence of gold, chromite and magnetite minerals. Fire assay for gold content give 1.04 g/ton .Chromite occurs as anhedral crystal associated with magnetite (Plate.4e). Chromite existed in different forms; zoned veinlet or disseminated specks (Plate. 4 fg). Black minerals filling fracture and associated with quartz (Plate.4h) . Fig. (6): showing different types of copper minerals in red and black jasper ,a) atacamite mineral, b) paratacamite mineral, c) cuprite mineral and d) crysocolla mineral . Fig. (7): Photograph showing copper minerals from black jasper of the study area. Alterations Two phases of hydrothermal alterations; acid and alkaline were distinguished in the shear zone resulting in Kaolinization and ferrugination processes as illustrated below: Kaolinization indicates that the rocks were affected by acidic solution with low temperature varying from 200 to 250  °C (Helgeston 1974). Kaolinitization process causes an increase in alumina (18.2%) at the expense of the other major oxides (Table2).Kaolinization affects sheared granites in the shear zone are characterized by the formation of clay minerals and adsorbed secondary U- minerals( meta-autunite, Kasolite and Phurcalite) (Table1). Acidic alteration of biotite produces illite+quartz ,while magnesium, iron, oxygen, and fluorine are dissolved in hydrothermal fluids (Pirajno,1992). These solution caused the alteration of the feldspars and micas to clay minerals (Fig.8) are produced by an acidic fluid and it liberates silica and K+ according to Pirajno,(1992). Similarly, the anorthite component of plagioclase is transformed to (clay minerals) (Hemley and Jones, 1964; Pirajno1992) and frees Ca2+ ions transported also by the hydrothermal solution. The free Al+3 increase the alumina in the clay mineral. This kind of alteration by acid solution is responsible for transported and redeposited uranium and base metals mineralization in WNW-ESE shear zone which acts as a good trap. carbonitization:The common presence of calcite manifesting carbonitization process along the shear zone (Fig.8).Also both of ultramafic -mafic rocks and intrusive gabbros are rich by carbonate minerals. Ferrugination causes increase in total Fe2O3 content (FeOt= 4.7%. to 32.7%) at the expense of other oxides. The strong alkaline solution may precipitate Fe+3 and U+6 within the shear zones in the form of iron oxy-hydroxides rich in uranium (Cuney, et al., 1984). Sheared granite samples stained by Fe oxides adsorb U minerals at the main shear zone. Ferrugination is represented mainly by hematite and goethite minerals (table1, Fig.9).Oxygen may combine with iron to produce hematite forming hematitic alteration. Plate 4: Photomicrographs showing; a) brecciated red jasper vein, C.N., X=40., b ) brecciated black jasper vein with vugs, c) black silica vein showing hematitization in quartz, iron oxide occurs as needles in quartz. C.N., X=40, d) blood red, Cr spinel having darker boundaries in BJV (PPL), X=20., e) chromite (cr) in rim and magnetite (mag) in core in BJV. X =40, f) veinlet of chromite and groundmass of magnetite in BJV. X=40, g) disseminated specks of chromite in BJV. X= 40, h) red jasper vein showing iron oxide present as black crystalline minerals and staining of quartz. C.N., X=20 fluoritization :Fluorite was emplaced through the fractures and fissures in altered granite along the shear zone. The released 3Ca2+and 6 Fà ¢Ã‹â€ Ã¢â‚¬â„¢ during illitization of the anorthite and biotite may combine together forming fluorite which is observed within the shear zone associate with U- minerals. Acknowledgements Our sincere thanks and gratitude should be provided to Dr.I, Hassan and Dr.W. El-Gazlawy, NMA, for their help during field work. Discussion Conclusion 1-To form a hydrothermal deposit in Um Bakra- Um Samra WNW-ESE shear zone requires: (1) a magma source of fluid, (2) dissolved metals in the magmatic fluids, , (3) heat source and activate tectonic, causes the migration of à ¯Ã‚ ¬Ã¢â‚¬Å¡uid and (4) Presence of channel ways, layering and physical cavities, to precipitates the metals or minerals. 2-G. Um Samra -G. Um Bakra shear zone strikes N-80 ° and dipping 45 ° /SSW and ranges from 30 to 500 m in thickness and extends 10 km in length. The host rock (syenogranites)is highly altered, fine -grained,ferruginous ,reddish pink and grayish pink to grayish in color. Two opposite N-S strike-slip faults and NNE and NNW strike-slip faults dextral and sinistral sense of movement(good channel ways) forming grabben and horst structures respectively (6 km in length, 30 m in width, dipping 10 °-20 ° towards E or W) cut the shear zone. 3-Three generations of silica veins differ in color, mineralization and age are common. The first phase (youngest),is barren milky quartz veins, running WNW and dipping 70 °/ SSW direction , highly brecciated (2-5 Km in length, 0.25-3 m in width. The red jasper(second phase) has N 60 °-76 ° W trend, dipping 45 °/ SSW direction, fractured, fragmented, discontinuous, brecciated, (7km in length, 0.30-3 m in width) and rich in Cr, Ni, Sn, Zn and Cu- mineralization) .The third phase (oldest one) is represented by black jasper (1.8 km in length, 0.5-10 m in width, trends N75W ,dipping 50 °-65 ° /SSW and rich in Cr, Ni, and Au mineralization). 4-The black jasper more richer than red one in Ni (av.1004 -81ppm),Cr(av.8575 -853ppm),Zn (av.144 -80 ppm), Cu(av.1106- 35 ppm), Co(av.371-0.0 ppm), Au(1.4 -0.5 ppm) and U(av, à ¢Ã¢â€š ¬Ã‚ ¦Ãƒ ¢Ã¢â€š ¬Ã‚ ¦.ppm)respectively (Table ). 5-The presence of clay mineral (dickite:Al2Si2O5(OH)4) in quartz and jasper veins indicates a temperature environment higher than 200 °C. The mixing of volatile fluids with meteoric water and fluid- wall rock interaction result in changes in pH and oxygen activity and deposition of base metals. 6- Precipitation of hematite in shear zone and red jasper veins probably decreased the pH of the solution and rising acidic fluids. The sudden change in the pH and temperature of the fluids will lead to destabilization of base metal complexes favouring their deposition (Alexandrov et al., 1985). 7-The cooling of the hydrothermal solution decreases the solubility of the metals. Cooling can take place when hot magmatic à ¯Ã‚ ¬Ã¢â‚¬Å¡uids enter cooler wall rocks or when two à ¯Ã‚ ¬Ã¢â‚¬Å¡uids mix, Similar reactions can take place between hydrothermal solutions and wall rock; a solution containing dissolved sulà ¯Ã‚ ¬Ã‚ de might contact a rock containing magnetite, to convert the magnetite to pyrite by a process called sulà ¯Ã‚ ¬Ã‚ dation.Or, a solution containing Cu might react with a rock containing pyrite to form Cu sulà ¯Ã‚ ¬Ã‚ des. 8- The base metals mineralization are accumulate in the residual melt of the late fractionate alkali feldspar granites (Bright, 1974) especially upward in the magmatic system (Smith,1979). During the emplacement of the basic and intermediate dikes (olivine basalt, andesite and dolerite dikes) which accompanied with high temperature and Co2), the base metals(galena, pyrite, sphalerite and cassiterite) were precipitated from saline and reduced fluids as sulfides due to cooling, fluid mixing and wall rock reaction. 9-The banded texture in jasper veins is common in epithermal base metals, indicating of boiling event and rapid deposition (Hedenquist et al.,1995).Most epithermal deposits consist of numerous separate, largely vertical veins that form a conjugate set, sometimes reà ¯Ã‚ ¬Ã¢â‚¬Å¡ecting regional tectonic stress. Low-temperature hydrothermal solutions ( 10- The non-sulfide ore deposits are classified into two major types; supergene and hypogene deposits (Hitzman et. al., 2003). (a) Supergene deposits form primarily from the oxidation of sulfide-bearing deposits and are formed principally zinc carbonate or silicates, and (b) hypogene deposits consist dominantly of zinc silicates and oxides, and they commonly result from mixing of a reduced, Zn-rich, with an oxidized, sulfur-poor fluid. Um Bakra-Um Samra shear zone containing zinc oxides (hypogene deposits). 11-Pyrite presents in two generations, disseminated and along fractures. The occurrence of covellite, bornite and magnetite are related to the oxidation product of disseminated pyrite, whereas the second type of pyrite transformed into pyrrhotite. 12-The chloritization process is the last phase of alteration in the shear zone, where fluids became rich in Mg/Fe most probably due to the decomposition of ferromagnesian minerals from the basic and intermediate dikes. Fig.( 8) :Showing Kaolinization map for Um Bakra -Um Samra area. Fig.( 9) showing ferrugination map for Um Bakra -Um Samra area. Table ( 2 ) chemical analysis of major oxides and trace elements of Um Samra-Um Bakra area. Trace elements (ppm) Fresh Altered Red Black Ni Range 0.0-55 0-18095 0-409 314-1501 Average 10 2322 81 1004 Cr Range 233-485 113-2409 294-2689 3490-12898 Average 296 798 853 8575 Rb Range 83-210 0-392 0.0-1161 0.0 Average 147. 128 289 0.0 Sr Range 17-507 73-58 8-127 0-17 Average 142 278 74 7 Zr Range 89-659 196-1873 0-466 0.0 Average 316 759 238 0.0 Y Range 16-102 84-512 0-79 0-142 Average 69 220 38 77 Nb Range 14-56 0-62 0-35 0.0 Average 36 10 11 0.0 Ga Range 22-45 0-151 0-59 0.0 Average 32 73 24 0.0 Zn Range 16-145 0-2409 32-169 56-281 Average 78 528 80 144 Pb Range 0-52 0-684 0-173 0.0 Average 16 157 45 0.0 Cu Range 0-32 0-210 0-80 431-2045 Average 4 26 35 1107 Co Range 0.0 0.0 0.0 0-558 Average 0.0 0.0 0.0 371 Mo Range 0.0 0.0 0-127 0.0 Average 0.0 0.0 25 0.0 As Range 0.0 0.0 0-2098 0.0 Average 0.0 0.0 419 0.0 U Range 0.0 0-7640 0.0 0.0 Average 0.0 1749 0.0 0.0 Major oxides % Fresh Altered Red Black SiO2 Range 69.22-75.33 23.14-72.09 70.3-92.53 72.93-91.27 Average 72.9 52.8 84.2 82.7 TiO2 Range 0.01-0.29 0.28-2.46 0.01-0.22 0.0 Average 0.2 1.08 0.2 0.0 Al2O3 Range 12.35-15.4 10.37-18.02 0.69-14.85 0.69 Average 13.7 12.7 6.8 0.8 Fe2O3 Range 0.08-2.91 2.10-45-77 1.39-4.97 4.46-22.54 Average 1.9 19.8 3.4 13.4 MnO Range 0-0.08 0-0.75 0.01-0.03 0.01-0.04 Average 0.03 0.1 0.03 0.03 MgO Range 0.13-0.65 0.24-7.23 0.29-1.75 0.19-0.60 Average 0.31 1.32 0.806 0.442 CaO Range 0.45-2.55 1.26-4.4 0.31-0.76 0.01-1.74 Average 1.1 2.6 0.6 0.5 Na2O Range 3.15-4.34 0.12-3.34 0.05-2.2 0.05-0.12 Average 3.7 0.8 0.6 0.08 K2O Range 4-6.70 1.84-7.78 0.1-6.96 0.04-0.09 Average 5 5 3 0.06 P2O5 Range 0.020.16 0.01-1.23 0.07-0.48 0.02-0.04 Average 0.08 0.39 0.224 0.032 L.O.I. Range 0.04-0.85 0.8-2.80 Average 0.31 1.43 Total Range 99.73-99.9 93.22-99.91 99.36-99.92 97.45-99.01 Average 100 98.42 99.7 98.288 References Abdalla, H. M., Matsueda, H., Obeid, M., A. and Takahashi., R., (2008): Chemistry of cassiterite in rare metal granitoids and the associated rocks in Eastern Desert, Egypt. Journal of Mineralogical and petrological sciences, 103, 318-326. Abdalla, H. M. and Mohamed, F. H., (1999): Mineralogical and geochemical investigation of emerald and beryl mineralization, Pan-African Belt of Egypt genetic and exploration aspects: J. Afr Earth Sci, 28,3, 581-598. Bakhit, F.S., 1978 geology and radioactive mineralization of Gabal El-Missikat area,Eastern Desert of Egypt, A.R.E. Ph.D. thesis, Fac. Sci., Ain Shams Univ., Cairo, Egypt, 289 p. Bakhit, F.S., and Meleik, M.L.,1990. Application of autocorrelation function to structural lineaments in radioactive sample area in the Central Eastern Desert of Egypt. Int. G. Remote Sensing, 11, No. 10,1919. El Ramly, M.F. (1972): A new geological map for the basement rocks rocks in the South Western Desert of Egypt. Ann. Geol. Surv. Egypt.2, 1-18. Gharieb A.G.

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